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Question

A piece of Al weighing 27 g is reacted with 200 mL of H2SO4 (specific gravity = 1.8 and 54.5 by weight). After the metal is completely dissolved, 73 g HCl is added and solution is further diluted to 500 mL solution. Find the concentration of H+ ion in mol/litre.

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Solution

Molarity of H2SO4 =1.8×54.5×1098=10 M

2Al1 mole+3H2SO42 moleAl2(SO4)3+3H2
Here Al is limiting reagent.
Moles of H2SO4 left =21.5=0.5
Moles of HCl added =2
Final volume of the solution =500 mL
Moles of H+ ion =3
Concentration of H+ =6 M

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