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Question

A piston-cylinder device initially contains 0.07m3 of nitrogen gas at 130 kPa and 120oC. The nitrogen is now expanded polytropically to a state of 100 kPa and 100oC. Determine the Boundary work of the process.

A
1.86 kJ
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B
1.68 kJ
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C
6.81 kJ
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D
8.18 kJ
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Solution

The correct option is B 1.86 kJ
Initial pressure=Pi=130 kPa, initial temperature= Ti=393 K, initial volume=Vi=.07 m3
Final pressure=Pf=100 kPa, final temperature=Tf=373 K, final volume=Vf

For polytropic process, PVx=constant
Here PiVxi=PfVxf ..........(i)
Applying ideal gas equation, Vf=(PiViTf)(TiPf)=130×.07×373393×100
Vf=0.086m3
Hence putting these values in (i),
x=1, i.e. PV=constant process is isothermal.
Hence work done = PiVilnVfVi=1.86 kJ

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