A piston-cylinder device initially contains 0.07m3 of nitrogen gas at 130kPa and 120oC. The nitrogen is now expanded polytropically to a state of 100kPa and 100oC. Determine the Boundary work of the process.
A
1.86kJ
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B
1.68kJ
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C
6.81kJ
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D
8.18kJ
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Solution
The correct option is B1.86kJ Initial pressure=Pi=130kPa, initial temperature= Ti=393K, initial volume=Vi=.07m3 Final pressure=Pf=100kPa, final temperature=Tf=373K, final volume=Vf
For polytropic process, PVx=constant Here PiVxi=PfVxf ..........(i) Applying ideal gas equation, Vf=(PiViTf)(TiPf)=130×.07×373393×100 ⇒Vf=0.086m3 Hence putting these values in (i), x=1, i.e. PV=constant → process is isothermal. Hence work done = PiVilnVfVi=1.86kJ