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Question

A piston-cylinder device initially contains 0.2 m3 neon (assume ideal) at 300 kPa inside at T2C. A valve is now opened and neon is allowed to escape until the volume reduces to half the initial volume. At the same time, heat transfer with outside at T2C ensures a constant temperature inside.
Select correct statement(s) for given process.
743918_1ddb818fed524a9c872b1ed7d0f5d78e.png

A
ΔU must be zero
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B
ΔU may not be zero
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C
q may be +ve
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D
q may be ve
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Solution

The correct options are
B ΔU may not be zero
C q may be +ve
D q may be ve
Given that:- 0.2m3Ne at 300kPa at T1
Vi=0.2m3
Vf=12Vi=0.1m3
Temperature inside the cylinder is constant as volume of gas is less and pressure is constant to maintain air temperature.
q may be ve or +ve.
ΔU0 as ΔnRT0
Hence (B), (C) and (D) are correct.

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