A piston cylinder device initially contains air at 125 kPa and 300 K. At this state,resting on a pair of stops and enclosed volume is 100 L. The mass of the pistor 250 kPa pressure is required to move it. The air is now heated till its volume be times. Use the following table.
T(K) | 300 | 600 | 900 | 1200 | 1500 |
u (kJ/kg) | 212 | 389 | 594 | 818 | 1114 |
m=PVRT
=125×0.1(0.287×300)=0.145kg
From ideal gas equation
P1V1T1=PsVsT3
⇒125×0.1300=250×0.25T3
⇒T3=1500K
Work done in the process=P2(V3−V2)
=250 (0.25-0.10) = 37.5kJ
from first law of thermodynamics
Q−W=ΔU=m(u3−u1)
Q=W+m(u3−u1)
=37.5 + 0.145(1114 - 212 ) =168.4 kJ