The correct option is A 1.03
From the formula of degree of freedom, we have,
Degree of freedom,
f=Translational DOF+Rotational DOF+Vibrational DOF
⇒f=3+3+24×2
Since, each vibrational mode has 2 degrees of freedom.
⇒f=54
Now, γ of the gas is given by,
γ=1+2f
⇒γ=1+254≈1.03
Hence, (A) is the required answer.