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B
2,4-Dimethyl aniline
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C
N-Methyl-o-methyl aniline
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D
p-Methyl benzylamine
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Solution
The correct options are B 2,4-Dimethyl aniline D p-Methyl benzylamine Two things you need to know/do here. 1) Carbylamine test is given by primary amines. 2) Figure out which ones of the options are actually primary amines. Remember, if there is a prefix 'N' before the name of an amine, it is clearly not a primary amine, you know this from the structure of amines. Therefore, 2,4-dimethyl aniline and p-methyl benzylamine will give positive carbylamine test. Their structures are given below: