The correct option is
D A primary, secondary or tertiary carbon atom
A primary amine has amine group
(−NH2) attached to a primary,
secondary or tertiary carbon atom
because a primary amine group is
directly bonded to one carbon of
any hybridization in the following
way
R−CH2−NH2 primary amine attach with
primary carbon
(R) 2 CH - NH 2 primary amine attach with
secondary carbon
R3−NH2 primary amine attach with
ternary carbon.