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Question

A quantity of 2 mol of helium gas undergoes a thermodynamic process, in which molar specific heat capacity (C) of the gas depends on absolute temperature T, according to relation:
C=3RT4T0
Where T0 is initial temperature of gas. It is observed that when temperature is increased, volume of gas first decreases and then increases. The total work done on the gas until it reaches minimum
volume is γδRT0 Find (γ+δ).

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Solution

According to given condition,
C=3RT4T0
We know
Cv=fR2
For helium degree of freedom, f=3
Cv=3R2
When it reaches minimum volume, the process can be treated as isochoric.
C=Cv
C=3RT4T0=3R2
T=2T0
From the first law of thermodynamics
δQ=dU+δW
2T0T0(2)3RT4T0=(2)3RT2(2T0T0)+W
6R4T0[T22]2T0T0=3RT0+W
W=9RT023RT0
W=3RT04
So, work done on the gas is 3RT04
Final answer: (7)



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