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Question

A radioactive isotope decays as zAmz2Bm4z1Cm4. The half lives of A and B are 6 months and 10 months respectively. Assuming that initially only A was present, will it be possible to achieve radioactive equilibrium for B. If so what would be the ratios of A and B at equilibrium. What would happen if the half lives A and B were 10 months and 6 months respectively.

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Solution

mZAαm4Z2Bβm4Z1C
(t1/2)A=10 month
(t1/2)B=6 month
The radioactive equilibrium is attached then, at equilibrium the ratio of atoms of A and B left is:
NANB=t1/2At1/2B=106=1.66
Therefore the answer is 2.
If half-life of A=6 month and B is 10 month, then since t1/2A<t1/2B or λA>λA and thus no equilibrium will be set.
Note: Radioactive process are first order in nature and any radioactive species completely decays only at infinite time.

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