When the ray of light is incident on the interface at 90 degrees, the angle of incidence, i = 0 degrees.
We know that, sin i = n * sin r {From Snells Law }
=> sin i = n*sin r = 0
=> sin r = 0
=> Angle of refraction , r = 0
Hence the ray passes through the glass air interface without any deviation.
Hope this helps :)