The correct options are
B Angle of deviation δ=π−4θ+2ϕ
C Angle of deviation δ=π
D For minimum angle of deviation ϕ<45∘
δ=δrefraction1+δreflection+δrefraction2=(ϕ−θ)+(π−2θ)+(ϕ−θ)=π+2ϕ−4θ
By snells law,
n1=sin ϕsin θ⇒√3=sin 60sin θ⇒θ=30∘
δ=π+2×60∘−4×30∘=π
δ=π+2ϕ−4θ………(1) and n=sin ϕsin θ
dϕdθ=ncosθcosϕ
⇒dϕdθ=n√1−sin2θcosϕ
⇒dϕdθ=ncos ϕ√1−sin2 ϕn2
By (1) dδdϕ=0⇒2 dϕ=4 dθ
dϕdθ=2⇒ncos ϕ√1−sin2 ϕn2=2
1−sin2 ϕn2=4 cos2 ϕn2⇒cos ϕ=√23
ϕ<45∘ [ϕ≈35∘]