A reaction mixture containing H2,N2 and NH3 has partial pressures 2 atm, 1 atm and 3 atm respectively at 725 K. If the value of Kp for the reaction, N2(g)+3H2(g)⇌2NH3(g) is 4.28×10−5atm−2 at 725 K, in which direction the net reaction will go?
A
Forward
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B
Backward
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C
No net reaction
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D
Direction of reaction cannot be predicted
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Solution
The correct option is B Backward The given reaction is, N2(g)+3H2(g)⇌2NH3(g) Kp=4.28×10−5atm−2QP=(PNH3)2PN2×(PH2)3=(3)2(1)(2)3 Qp=98atm−2=1.125atm−2. Since value of QP is larger than KP(4.2810−5atm−2), it indicates net reaction will proceed in backward direction.