A reaction S8(g)⇌4S2(g) is carried out by taking 2 moles of S8(g) and 0.2 mole of of S2 in the reaction vessel of 1 litre and temperature 6270C. Which of the following option(s) is/are correct if Kc=6.30×10−6? (Given: R= 0.08 atm−L/molK)
A
Reaction quotient is 8×10−4
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B
Reaction proceeds in backward direction
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C
Kp=2.35atm3
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D
Reaction proceeds in forward direction
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Solution
The correct options are A Reaction quotient is 8×10−4 B Reaction proceeds in backward direction CKp=2.35atm3 Reaction quotient Q=[S2]4[S8]=(0.2)42=8×10−4 As Q>Kc, reaction will go backwards. Kp=Kc×(RT)Δng Kp=6.3×10−6×(0.08×900)3=2.35atm3