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Question

A reaction S8(g)4S2(g) is carried out by taking 2 moles of S8(g) and 0.2 mole of of S2 in the reaction vessel of 1 litre and temperature 627 0C. Which of the following option(s) is/are correct if Kc= 6.30×106? (Given: R= 0.08 atmL/molK)

A
Reaction quotient is 8×104
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B
Reaction proceeds in backward direction
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C
Kp=2.35 atm3
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D
Reaction proceeds in forward direction
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Solution

The correct options are
A Reaction quotient is 8×104
B Reaction proceeds in backward direction
C Kp=2.35 atm3
Reaction quotient Q=[S2]4[S8]=(0.2)42=8×104
As Q>Kc, reaction will go backwards.
Kp=Kc×(RT)Δng
Kp=6.3×106×(0.08×900)3=2.35 atm3

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