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Question

A reaction takes place in three steps. The rate constants are k1,k2andk3. The over all rate constant
k=k1k3k2. If (energyofactivation)E1,E2andE3are60,30and10kJ.
The overall energy of activation is:

A
40
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B
30
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C
400
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D
60
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Solution

The correct option is A 40
As we know,
k=AeEa/RT
AeEa/RT=Aeε1ε3+ε2RT
εa=E1+E3E2=60+1030=40kJ

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