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Question

A red solution is obtained when ferric chloride solution is added to sodium extract. It indicates both nitrogen and sulphur are present in the organic compound.

A
True
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B
False
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Solution

The correct option is A True
Ferric Chloride (FeCl3) that reacts with Sodium Thiocyanate (NaCNS) to form Ferric Thiocyanate [Fe(CNS)3] which is blood red in color. This test can be used as a confirmatory test for organic compounds containing both Nitrogen and Sulfur (e.g. Methionine amino acid).

NaCN+S8ΔNaSCNSodium Thiocynate

Fe+3+3NaSCNFe(SCN)3 Ferric thiocynate(Blood red colouration)

Hence the correct answer is the option (A)


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