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Question


A rose-coloured compound has the empirical formula CoCl2.5NH3.H2O. Two moles of this compound react with concentrated sulphuric acid to form HCl(g) and one mole of a new compound with empirical formula Co2(SO4)3.10NH3.5H2O. When this new compound is dried at room temperature, it loses three moles of water per mol of Co2(SO4)3.10NH3.5H2O.

What is the formula of the rose-coloured compound?

A
[Co(NH3)5Cl]Cl2H2O
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B
[Co(NH3)5H2O]Cl2
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C
[Co(NH3)5(H2O)Cl2]Cl
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D
None of the above.
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Solution

The correct option is B [Co(NH3)5H2O]Cl2
As rose colored compound forms two mole of HCl with sulphuric acid so compound is :

[Co(NH3)5H2O]Cl2H2SO4−−−2HCl+[Co(NH3)5H2O]SO4

Therefore, option B is correct.

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