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Question

A sample of 100 g H2O is slowly heated from 27oC to 87oC. The change in entropy during heating is x J. Then 100x is _____.

[Specific heat of water = 4200J/(kg.K)]

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Solution

Entropy can be defined as a thermodynamic quantity representing the unavailability of a system's thermal energy for conversion into mechanical work, often interpreted as the degree of disorder or randomness in the system.

When the temperature is increased the change in entropy can be calculated as
δS=mCp(l)δT/T

Integrating from T1 to T2, we get

ΔS=mCP(l)lnT2T1

Given
T1=27oC=300K
T2=87oC=360K
Mass of water =100g=0.1Kg
Specific heat of water =4200J/(Kg.K)

ΔS=0.1×4200×ln360300

ΔS=76.57J=x

100x=7657

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