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Question

A sample of air contains nitrogen, oxygen and saturated with water vapour under a total pressure of 640 mm. If the vapour pressure of water at that temperature is 40 mm and mole ratio of N2 : O2 is 3:1, the partial pressure of nitrogen in the sample is:

A
480 mm
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B
600 mm
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C
450 mm
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D
160 mm
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Solution

The correct option is B 450 mm
Aqueous tension = 40mm
Pressure due to N2 and O2 = 64040=600mm
Mole fraction of N2=3:4
Partial pressure of N2= Mole fraction of N2× Total pressure
Partial pressure N2 is 34×600=450

Hence, the correct option is C

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