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Question

A sample of calcium carbonate is 80% pure, 25 gm of this sample is treated with excess of HCl. How much volume of CO2 will be obtained at 1 atm & 273 K?

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Solution

The mass of pure CaCO3=80100×25=20g
CaCO3(s)+2HCl(aq)CaCl2(s)+CO2(g)+H2O(l)
The mole ratio of calcium carbonate and CO2 is 1:1
Moles of CaCO3=MassofCaCO3Molarmass=20100=0.2 moles
Moles of CO2=0.2 moles
Molar gas volume 1 mole =22.4 litres
0.2 mole =2×22.4=4.48 litres.
4.48 litres of CO2 will be obtained.

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