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Question

A sample of chalk contains clay as impurity. The clay impurity loses 11% of its weight as moisture on prolong heating. 5 gram sample of chalk on heating shows a loss is weight (due to evolution of CO2 and water) by 1.1 g. Calculate % of chalk (CaCO3) in the sample.

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Solution

Let the mass of chalk in 5g be x grams,

Therefore, mass of clay = (5 - x) grams.

Mass of moisture lost by clay = (5 - x) x 11100

= (0.55 - 0.11x) grams.

Now,

CaCO3Heat−−−−−CaO+CO2

Molar mass of CaCO3 is 100g, loss its mass by 44 g in the form of CO2 gas

Therefore,

44 g of CO2 is lost by 100 g chalk

So,

x gram CO2 is lost by 44100 is multiplied by x = 0.44x grams

Total mass lost from 5 g of chalk/clay = 1.1g

Therefore,

(0.55 - 0.11x) + 0.44x grams = 1.1g

0.33x = 1.1 - 0.55

0.33x = 0.55

x = 1.67g

Hence, % of chalk in sample = 1,675 x 100

= 33.4 %

Chalk (CaCO3) release CO2 on heating.

33% CO2 IS LOSS

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