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Question

A sample of drinking water was found to be severely contaminated with chloroform (CHCl3). Supposed to be carcinogenic in nature. The level of contamination was 15 ppm (by mass).

(i) Express this in percentage by mass.

(ii) Determine the molality of chloroform in the water sample.

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Solution

Part (i): Calculating the percentage by mass

ppm by mass is the amount of solute in 106g of solution.

Given:

Concentration =15ppm

Now, 106g of solution contains =15g of CHCl3

Hence; 100g of solution contain =15/106×100

=15×10−4=0.0015%

Part (ii): Calculating the molality of chloroform

Molar mass of chloroform =119.5g/mol

Mass of solvent =1000000−15=999985g

Molality=Molesofsolute/Mass of solvent×1000

m=15119.5×999985×1000

m=1.266×10−4m


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