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Question

A sample of naturally occurring silicon con­sists Si-28 (27.9769u), Si-29 (28.9765u) and Si-30 (29.9738u). If the atomic mass of silicon is 28.0855 and the natural abundance of Si-29 is 4.67%, what are the natural abundances of Si-28 and Si-30?


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Solution

Given:

Atomic mass of Si=28.0855.

Atomic mass of Si-28=27.9769u

Atomic mass of Si-29=28.9765u

Atomic mass of Si-30=29.9738u

Natural abundance of Si-29=4.67%

Formula used:

Atomicmass=Abundanceofisotope1100×At.massofisotope1+Abundanceofisotope2100×At.massofisotope2+Abundanceofisotope3100×At.massofisotope3

Calculate the natural abundance of Si-28:

Let the natural abundance of Si-28 be x.

Then the natural abundance of Si-30 will be =100-4.67-x=95.33-x

Thus,

Atomicmass=Abundanceofisotope1100×At.massofisotope1+Abundanceofisotope2100×At.massofisotope2+Abundanceofisotope3100×At.massofisotope328.0855=x100×27.9769+4.67100×28.9765+95.33-x100×29.973828.0855=0.279769x+1.3532+28.57-0.299738x1.8377=0.019969xx=92.03

Therefore, natural abundance of Si-28 is 92.03%.

Calculate the natural abundance of Si-30:

Natural abundance of Si-30=95.33-x

Thus,

Natural abundance of Si-30=95.33-92.03

Natural abundance of Si-30=3.31%

Therefore, natural abundance of Si-30 is 3.31%.


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