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Question

A sample of pure NO2 gas heated to 1000 K decomposes: 2NO2(g)2NO(g)+O2(g). The equilibrium constant KP is 100 atm. Analysis shows that the partial pressure of O2 is 0.25 atm at equilibrium. The partial pressure of NO2 at equilibrium is:

A
0.03
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B
0.25
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C
0.025
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D
0.05
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Solution

The correct option is D 0.05
2NO2(g)2NO(g)+O2(g)
At t=0 Po
At time t Po2x 2x x
Given, x=0.25 atm
Kp=(2x2)×x(Po2x)2
100=4x2(Po2x)2
5=xPo2x
5Po=11x=11×0.25
Po=0.55
Pressure of NO2 at equillibrium =Po2x
0.552(0.25)
=0.05 atm

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