The correct option is D Extrinsic semiconductor
A semiconductor diode consists of p-n junction having metallic contacts at both the ends. A single piece of a semiconductor material (either Si or Ge) with one portion doped with a pentavalent impurity and other portion doped with trivalent impurity behaves as a p-n junction. Means, extrinsic semiconductor or semiconductor doped with impurities of both p and n are used in p-n junction diode.