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Question

A silicate mineral has three SiO4 tetrahedral that share corners with adjacent tetrahedral. Mineral also contains Ca2+,Cu+ and H2O in 1:1:1 molar ratio. Thus, total number of atoms of Cu,Si and Ca per unit of mineral is :

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Solution

When three SiO4 tetrahedral share corners with adjacent tetrahedral, (Si3O9)6 ion is obtained. The -6 charge is balanced by two Cu+ ions and two Ca2+ ions. Thus, there are 3 Si atoms, 2 Cu atoms and 2 Ca atoms per unit of mineral. Hence, the total number of atoms of Cu, Si and Ca is 3+2+2=7.

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