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Question

A single epoxide was isolated in 7984% yield in the following reaction. Was this epoxide A or B?
1) A
2) B

236668_0ff5e559b7974d319127c63793d5205e.png

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Solution

In this reaction, the epoxide B is formed as epoxidation occurs at more electron-rich olefinic bond. In B, the olefinic bond that is epoxidized is tetrasubstituted and electron-rich due to +I effect of four alkyl groups.
258969_236668_ans_2440bf5244ae42e4b097db5dd69ca011.png

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