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Question

A slice of banana weighing 2.502 g was burnt in a bomb calorimeter
producing a temperature rise of 3.05C. The combustion of
0.316 g of benzoic acid in the same calorimeter produced a temperature
rise of 3.24C. The heat of combustion of benzoic acid at
constant volume is 3227kJmol1. If average banana mass
is 125 g, the kilojoules of energy can be obtained from 1 average
banana is

A
393
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B
350
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C
450
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D
850
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Solution

The correct option is A 393
q=mS.ΔT for combustion of benzoic acid
(Note: In bomb calorimeter reaction is made at constant volume)
0.316×3227122=m×S×3.24
Water equivalent of bomb calorimeter (mS)
=0.316×3227122×3.24=2.58kJ/C
For banana slice; q=mS×ΔT
q=2.58×3.05
=7.87kJper2.502gbanana
Heatproducedby125gbanana=7.87×12.52.502=393.18kJ
so nearest integer value is 393.

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