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Question

A small amount of ethyl alcohol is added to brine solution in the Nelson’s Cell is closed and electrolyzed. The final organic product formed is.


A

CH3CHO

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B

CCl3CHO

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C

CHCl3

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D

CCl3COOH

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Solution

The correct option is C

CHCl3


Chlorine at anode oxidises ethanol to chloral C2H5OH+4Cl2CCl3CHO+5HCl,
Chloral on base hydrolysis with caustic soda finally gives chloroform
CCl3CHO+NaOHHCOONa+CHCl3


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