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Question

A solid has a structure in which 'W' atoms are located at the corners of a cubic lattice 'O' atom at the center of the edge and Na atoms at the center of the cube. The formula for the compound is:

A
Na2WO3
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B
Na2WO2
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C
NaWO2
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D
NaWO3
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Solution

The correct option is D NaWO3
In a unit cell, W atoms at the corner =18×8=1

O-atoms at the centre of edge =14×12=3

Na atoms at the center of the cube =1

W:O:Na=1:3:1

Hence, formula=NaWO3

So, the correct option is D

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