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Question

A solid is made of two elements P&Q. Atoms P are in ccp arrangement and atoms Q occupy all the octahedral voids and half of the tetrahedral voids, then the simplest formula of the compound is


A

PQ2

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B

P2Q

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C

PQ

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D

P2Q2

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Solution

The correct option is A

PQ2


Four atoms (P) contributes to one unit cell from ccp arrangement and 4-atoms (Q) from the all octahedral
voids and 4-atoms (Q) from the half of the tetrahedral void contributes one unit cell.

So, formula of solid is P4Q8 so, the simplest formula of the solid is PQ2


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