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Question

A solution contains 410.3 g of H2SO4 per litre of solution at 20oC. If the density is 1.243g/mL, what will be its molarity and molality?

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Solution

Mol. mass of H2SO4=98

No. of moles of H2SO4=410.398=4.186

Molarity of H2SO4 solution =No.of moles ofH2SO4Volume of sol.in litre

=4.1861=4.186M

Mass of 1 litre H2SO4 solution =1000×1.243=1243g

Mass of water =(1243410.3)=832.7g=832.71000kg

Molality of solution =No.of moles ofH2SO4Mass of water in kg

=4.186832.7×1000

=5.027m

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