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Question

A solution contains Na2CO3 and NaHCO3.10 ml of the solution requires 2.5 ml of 0.1M H2SO4 for neutralisation using phenolphthalein as an indicator. Methyl orange is added when further 2.5 ml of 0.2 M H2SO4 is required. The amount of NaHCO3 in one litre of the solution is

A
2.1g
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B
8.4 g
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C
5.3 g
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D
4.2 g
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Solution

The correct option is D 4.2 g
No.meq Na2CO3No.meq NaHCO32.5×0.1×2=0.5 meqNo.of meq NaHCO3+No.of Meq NaHCO3=2.5×0.2×2=1.0meq(formed from Na2CO3)0.5+No.of meq NaHCO3=1.0No.of meq NaHCO3=0.5 meqW84×1000=0.5,W=0.5×84100010 ml of solution has0.5×841000g100 ml0.5×841000×100010=4.2 g/lit

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