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Question

A solution is 0.1 M in each KCl, KBr and K2CrO4. To this solution solid AgNO3 is gradually added. Assume no change in the volume of the solution.
Given: Ksp(AgCl)=1.7×1010
Ksp(AgBr)=5×1013
and Ksp(Ag2CrO4)=1.9×1012

The concentration of [Ag+] required to start the precipitation of AgBr is:

A
5×1012 M
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B
1.7×109 M
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C
6×1011 M
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D
4×108 M
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Solution

The correct option is A 5×1012 M

[Ag+] to start the precipitation of Br=Ksp(AgBr)[Br]=5×10130.1=5×1012 M


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