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Question

A solution of 1.25 g of a certain non-volatile substance in 20 g of water freezes at 271.94 K. Calculate the molecular mass of the solute (Kf=1.86 K.kg.mol1).

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Solution

Freezing point of the solution =271.94 K
Freezing point of water =273.0 K

T=(273271.94)=1.06K

We know that,

m=1000Kf×wW×T

Given,
Kf=1.86 Kkgmol1,
w=1.25g,
W=20g ,
T=1.06K

Now,

M=1000×1.86×1.2520×1.06

M=109.67 g/mol

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