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Question

A solution of a metal ion when treated with KI gives a red precipitate which dissolves in excess KI to give a colorless solution. Moreover, the solution of metal ion on treatment with a solution of cobalt (II) thiocyanate gives rise to a deep-blue crystalline precipitate. The metal ion is :

A
Pb2+
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B
Hg2+
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C
Cu2+
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D
CO2
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Solution

The correct option is B Hg2+
Option (B) is correct.
The metal ion is Hg2+.
Hg2++2IHgI2 (Scarlet red precipitate)

HgI2+2I[HgI4]2

Hg2++Co(SCN)2Hg(SCN)2+Co2+Deepbluecrystalline

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