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Question

A solution of a metal ion when treated with KI gives a red precipitate which dissolves in excess KI to give a colourless solution. Moreover, the solution of metal ion on treatment with a solution of cobalt (II) thiocyanate gives rise to a deep blue crystalline precipitate. The metal ion is:

A
Pb+2
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B
Hg+2
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C
Co+2
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D
Cu+2
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Solution

The correct option is B Hg+2
Hg+2 reacts with KI to form red ppt which dissolves in excess KI to form colourless solution.
Hg+2reacts with [Co(SCN)4]2to give blue complex.


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