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Question

A solution of potassium chloride in water is 35%(m/v). The density of the solution is 1.2gmL-1. Calculate the concentration of the solution in %(m/m)


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Solution

Step-1: Calculate the mass of the given solution

It is given that solution of Potassium chloride (KCl) has a concentration of 35%(m/v).

  • m/v represents mass by volume. It is a way to represent the concentration of the solution.
  • It is defined as the mass of the solute in g dissolved in per 100mL of the solution.
  • 35%(m/v) can be interpreted as 35g of Potassium chloride (solute) is present in 100mL of the solution according to the formula given below:

A solution comprises two parts i.e.; solute and solvent

  • Solute: The component of the solution to be dissolved or the component present in the solution in a lesser quantity.
  • Solvent: The component of the solution that dissolves or the component present in the solution in a larger quantity.

Concentrationin(m/v)%=Massofthesolute(g)Volumeofthesolution(mL)×100……(i)

  • To calculate the concentration in %(m/m), the mass of the solution needs to be calculated first which can be done using the density of the solution.
  • Densityofthesolution=Massofthesolution(g)Volumeofthesolution(mL)……..(ii)
  • Given, Density= 1.2gmL-1
  • The volume of the solution= 100mL ……..interpreted from (m/v)
  • Substituting the values in the formula (ii)
  • 1.2=Massofthesolution100
  • Massofthesolution=1.2×100=120g

Step-2: Calculate the concentration of the solution in %(m/m)

The formula used to calculate the concentration in %(m/m) is given below:

Concentrationin(m/m)%=Massofthesolute(g)Massofthesolution(g)×100

  • m/m represents mass by mass. It is a way to represent the concentration of the solution.
  • It is defined as the mass of the solute in g dissolved in per 100g of the solution.

Mass of the solute= 35g (interpreted above)

Mass of the solution= 120g (calculated above)

  • Concentrationin(m/m)%=35120×100=3500120=29.167%

Hence,concentrationofthesolutionin(m/m)%=29.167%(m/m)


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