A solution of which substance can best be used as both titrant and its own indicator in an oxidation-reduction titration?
Potassium Permanganate acts like a self indicator. In acidic medium KMnO4 gets itself converted into Mn2+ ion which is pink in colour. So, the appearance of pale permanent pink colour will indicate the end point of the titration.So it acts as indicator and titrant.
Hence option D is correct.