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Question

A solution prepared by dissolving a 2.50g sample of an unknown compound dissolved in 34.0g of benzene,
C6H6 boils at 1.38C higher than pure benzene. Which expression gives the molar mass of the unknown compound
?
Compound Kb
C6H62.53C.m1

A
2.53×2.501.38
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B
1.38×34.02.53×2.50
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C
2.50×103×2.5334.0×11.38
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D
2.50×103×1.3834.0×2.53
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Solution

The correct option is B 2.50×103×2.5334.0×11.38
As we know,
M2=1000×Kb×w2ΔTbw1
M2=1000×2.53×2.51.38×34

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