A solution prepared by dissolving a 2.50g sample of an unknown compound dissolved in 34.0g of benzene, C6H6 boils at 1.38∘C higher than pure benzene. Which expression gives the molar mass of the unknown compound ? Compound Kb C6H62.53∘C.m−1
A
2.53×2.501.38
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B
1.38×34.02.53×2.50
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C
2.50×103×2.5334.0×11.38
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D
2.50×103×1.3834.0×2.53
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Solution
The correct option is B2.50×103×2.5334.0×11.38 As we know, M2=1000×Kb×w2ΔTbw1 M2=1000×2.53×2.51.38×34