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Question

A solution which is 103M each in Mn2+,Fe2+,Zn2+ and Hg2+ is treated with 1016M sulphide ion. If Ksp of MnS, FeS, ZnS, and HgS are 1015,1023,1020and 1054 respectively, which one will precipitate first?

A
FeS
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B
MgS
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C
HgS
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D
ZnS
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Solution

The correct option is C HgS
Salt having low Ksp precipitates first. Thus HgS will precipitate first.

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