Let r be the radius of the sphere and a be the side of the cube.
According to the question,
Surface area of cube = Surface area of sphere
⇒6a2=4πr2
⇒64π=r2a2
∴ra=√32π
Therefore,
Volume of sphere : Volume of cube =43π(√3)2(√2π)3
=4π√32π√2π
=√6√π