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Question

A steel vessel of capacity 22.4 litre contains 2 g of hydrogen, 8g of oxygen and 22g of carbon dioxide at a temperature of 0oC. The total pressure of the gas is:

A
1.75 atm
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B
1.25 atm
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C
1.50 atm
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D
1.00 atm
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Solution

The correct option is A 1.75 atm
2 g of hydrogen, 8g of oxygen and 22 g of carbon dioxide corresponds to
22=1 mole of hydrogen, 832=0.25 moles of oxygen and 2244=0.5 moles of carbon dioxide.
The total number of moles are =1+0.25+0.5=1.75 moles.
The temperature is 0+273=273K
The total pressure is P=nRTV
P=1.75×0.0821×27322.4=1.75atm.

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