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Question

A student performs a titration using 1.00 M NaOH to find the unknown molarity of a solution of HCl. The student records the data as shown below. What is the molarity of the solution of MCl?

Base: final burette reading 21.05 mL
Base: initial burette reading 6.05 mL
mL of base used
Acid: final burette reading44.15 mL
Acid: initial burette reading 14.15 mL
mL of acid used

A
0.75M
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B
0.50M
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C
0.25M
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D
0.10M
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E
2.00M
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Solution

The correct option is B 0.50M
According to the law of equivalence,
N1V1=N2V2
HCl and NaOH has normality equal to molarity (Monobasic and monoacidic)
M1V1=M2V2
Here M1= Molarity of base =1.0M
V1= volume of base used=21.056.05=15.0ml
M2= Molarity of acid=?
V2= Volume of acid used=44.1514.15=30ml
M2=M1V1V2=1×1530=0.50M

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