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Question

A student tested four unknown solutions of macromolecules with three reagents. She also tested the solubility of the solutions with water, a polar solvent, and hexane, a non-polar solvent. Her results are shown in the table below.

SolutionBenedict's SolutionBiuret SolutionIodineIodine Solubility
1
2
3
4
yes
no
no
no
no
no
yes
no
no
yes
no
no
water
water
water
hexane
Which of these correctly identifies the macromolecule found in each solution?

A
Solution 1: protein
Solution 2: starch
Solution 3: monosaccharide
Solution 4: lipid
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B
Solution 1: lipid
Solution 2: protein
Solution 3: starch
Solution 4: monosaccharide
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C
Solution 1: monosaccharide
Solution 2: protein
Solution 3: lipid
Solution 4: starch
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D
Solution 1: starch
Solution 2: monosaccharide
Solution 3: lipid
Solution 4: protein
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E
Solution 1:monosaccharide
Solution 2: starch
Solution 3: protein
Solution 4: lipid
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Solution

The correct option is E Solution 1:monosaccharide
Solution 2: starch
Solution 3: protein
Solution 4: lipid
I. Solution 1 is showing solubility in water and positive test for Benedict's solution. This means that it's a carbohydrate i.e. it could be a monosaccharide.
II. Solution 2 is showing solubility in water and positive test for Iodine. This means it's starch.
III. Solution 3 is showing solubility with water and positive test for Biuret solution. This means it's protein.
IV. Solution 4 is showing solubility in hexane, a non polar solvent and no positive test for any of the reagents. This means it's lipid solution.
So, the correct answer is :
Solution 1: monosaccharide
Solution 2: starch
Solution 3: protein
Solution 4: lipid

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