Volume of solute (acetone) =6 mL
Concentration (v/v%) of solution =30%
Let the volume of water (solvent) required to be x mL.
So, the volume of solution = Volume of solute + Volume of solution
= (6 + x) mL.
We know that,
Concentration of a solution (v/v%) =Volume of soluteVolume of solution×100
⇒66+x×100=30
⇒600=180+30x
⇒30x=600−180
⇒x=42030
x=14 mL