Phenolphthalein is a universal indicator, it is colorless in an acidic and neutral environment but shows pink color in a basic environment.
As it shows a pink color, the solution is basic. Therefore, to obtain a colorless solution again, the student needs to add an excess of the acidic solution in it. So, out of all the given options, only the HCl solution is suitable.
Hence, the correct answer is option 1.