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Question

A substance undergoes first order decomposition. The decomposition follows the parallel first order reaction as. The percentage distribution of B and C is

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A
76.83,23.17
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B
24.9,75.1
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C
60,40
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D
50,50
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Solution

The correct option is C 76.83,23.17
At any time t
Rate of formation of BCB=k1CA
Rate of formation of CCC=k2CA
CBCC=k1k2=1.26×1043.8×105
%CB=CBCB+CC×100=1.26×104(1.26×104+3.8×105)×100=76.83
%CC=100CB=10076.83=23.17

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