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Question

A system in thermodynamic equilibrium will have the minimum value for-?

A
Helmholtz free energy
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B
Gibb's free energy
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C
Entropy
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D
Temperature
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Solution

The correct options are
A Helmholtz free energy
B Gibb's free energy
A system is said to be in thermodynamic equilibrium when the macroscopic particles do not undergoes any change with time.
For a system in thermodynamic equilibrium, at controlled constant temperature and pressure, Gibb's free energy is minimum and at controlled constant temperature and volume Helmholtz's free energy is minimum.

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