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Question

A transition metal M forms a volatile chloride which has a vapour density of 94.8. If it contains 74.75% of chlorine the formula of the metal chloride will be:

A
MCl2
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B
MCl4
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C
MCl5
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D
MCl3
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Solution

The correct option is A MCl4
The correct option is B
Solution:
74.75 of chlorine mean 74.75g chlorine present in 100g of metal chloride.
Weight of metal=100g-74.75g=25.25g
Equivaent weight=weight of metal weight of chlorine ×35.5g
25.2574.75×35.5=12
valency of metal=2×V.Dequivalentweightofmetal+35.5×35.5=4
therefore formula of compound =MCl4

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