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Question

A typical sesquioxide of Rb/Rb4O6 can be represented as :

A
[Rb4(O2)2(O2)22]
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B
Rb4(O2)6
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C
RbO2,(Rb2O2)2
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D
Rb2O.(Rb2O2)2
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Solution

The correct option is A [Rb4(O2)2(O2)22]
A sesquioxide is an oxide containing three atoms of oxygen with two atoms of another element. Many sesquioxides contain the metal in the +3 oxidation state and the oxide ion, e.g., Al2O3,La2O3. The alkali metal sesquioxides are exceptions and contain both peroxide, (O22) and superoxide, (O2) ions, like Rb2O3 is formulated [(Rb+)4(O22)(O22)2].

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